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Intermolecular Interactions in Crystals

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書名

Intermolecular Interactions in Crystals: Fundamentals of Crystal Engineering
著者・編者 Novoa, J.
出版社/発行元 RSC Publications
発行年/月 2017年10月  
装丁 Hardcover
ページ数/巻数 805 ページ
ISBN 978-1-78262-173-7
発送予定 海外倉庫よりお取り寄せ 3-5週間以内に発送します

 

Desciption

 

The field of crystal engineering concerns the design and synthesis of molecular crystals with desired properties. This requires an in-depth understanding of the intermolecular interactions within crystal structures. This new book brings together the latest information and theories about intermolecular bonding, providing an introductory text for graduates. The book is divided into three parts. The first part covers the nature, physical meaning and methods for identification and analysis of intermolecular bonds. The second part explains the different types of bond known to occur in molecular crystals, with each chapter written by a specialist in that specific bond type. The final part discusses the cooperativity effects of different bond types present in one solid. This comprehensive textbook will provide a valuable resource for all students and researchers in the field of crystallography, materials science and supramolecular chemistry.

 

 

Contents

 

Part A: Basic concepts on intermolecular interactions
Intermolecular interactions and bonds in crystals. A general view
Theoretical models of the chemical and intermolecular bond
On the meaning of bonds
The importance of repulsive intermolecular interactions in crystals
Experimental detection of intermolecular bonds using STM techniques
Intermolecular bonds as seen from theoretical/experimental AIM analysis
Spectroscopic MW techniques for the study of intermolecular interactions
Spectroscopic vibrational techniques for the study of intermolecular interactions
Solid state NMR techniques for the study of intermolecular interactions
Quantitative determination of the nature of intermolecular bonds by EDA analysis
The statistical analysis of crystal structures: A tool to gain average information on the nature of intermolecular interaction
   
Part B: Major types of intermolecular interactions/bonds
Intermolecular electrostatic interactions in molecular crystals
The metal ligand bond in transition metal complexes
Hydrogen bonds. A theoretical perspective
Hydrogen bonds in crystals. A experimental perspective
Weak hydrogen bonds
Halogen bonds
Halogen···halogen interactions
Chalcogen···chalcogen, pnicogen and Be···Be bonds
Radical···radical intermolecular interactions

Part C: Intermolecular bonds in crystals
Revealing the intermolecular bonds in molecular crystals
Cooperativity in intermolecular interactions
Multivalency in intermolecular interactions
Cooperativity in hydrogen bonded crystals: Packing Motifs

 

 

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