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商品コード: 9783319440538

Lithium Metal Anodes and Rechargeable Lithium

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特集 > 電池

分野別 > 化学 > 物理化学

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書名

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries
著者・編者 Zhang, J.-G. et al.
出版社/発行元 Springer
発行年/月 2016年11月   
装丁 Hardcover
ページ数/巻数 194 ページ
ISBN 978-3-319-44053-8
発送予定 海外倉庫よりお取り寄せ 2-3週間以内に発送します

 

Desciption

 

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (?3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes.

In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

 

Contents:

 

1 Introduction

2 Characterization and Modeling of Lithium Dendrite Growth
2.1 Characterization of Lithium Dendrite Growth
2.2 Effect of SEI Layer on Lithium Dendrite Growth
2.3 Modeling of Lithium Dendrite Growth

3 High Coulombic Efficiency of Lithium Plating/Stripping and Lithium Dendrite Prevention
3.1 Coulombic Efficiency of Lithium Plating/Stripping
3.2 Electrolyte and In Situ Formed Solid Electrolyte Interphase
3.3 Ex Situ Formed Surface Coating
3.4 Mechanical Blocking and Solid Electrolytes
3.5 Effect of Substrates
3.6 Influence of Charge/Discharge Profiles
3.7 Effect of Rest/Storage Time
3.8 Effect of Temperature
3.9 Effect of Stack Pressure
3.10 Summary

4 Application of Lithium Metal Anodes
4.1 Lithium Metal Batteries with Lithium Intercalation Cathodes
4.2 Lithium Metal Anodes in Lithium?Sulfur Batteries
4.3 Lithium Metal Anodes in Lithium-Air Batteries
4.4 Anode-Free Lithium Batteries

5 Perspectives

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